Dr.
Chakrit Sirisinha has been working
on polymer rheology, rubber mixing
and rubber blends. For a study of
mixing behaviour, it has been found
that the filler dispersion (or the
so-called state-of-mix) plays an important
role in extrudate swell as well as
extrudate surface quality. Thus, by
controlling the degree of filler dispersion,
not only good processability and extrudate
quality, but also low mixing energy
and short mixing time could be achieved.
The addition of some additives such
as processing oil or slipping agent
could improve processability and extrudate
quality via the state-of-mix. Recently,
the investigation of the mixing behaviour
and its role in properties of different-grade
natural rubber (NR) and filler has
been of interest.
As for a study of rubber blend,
the results obtained reveal that filler
distributes unevenly in each phase
of the blend. Filler tends to reside
more in the phase with lower viscosity
and / or that with closer polarity
to the filler, which affects significantly
the mechanical properties of the blends.
In addition, for the unfilled blends,
the present research project aims
to maximise the use of MR, and the
results obtained show that phase morphology
in blends influences remarkably the
oil resistance in the blends between
nitrile rubber (NBR) and natural rubber
(NR), and those between chlorinated
polyethylene (CPE) and NR. The smaller
the phase size, the higher the resistance
to oil of the blends. |